#Acid pickling of martensitic steel how to#
#Acid pickling of martensitic steel cracked#

If it's contamination in the annealing I'm not sure how to test for this, nor am I sure how to rectify the situation. I'm leaning towards soft, rough surface reacting more easily with the pickling solution or contamination in the annealing. I use the same solution tank with a harder SS304 profiled wire and with a non annealed 304L wire from the same supplier. I'm not sure of the concentration of my pickling solution, we've never had any problems before so we've always just topped it up depending upon the results.

#Acid pickling of martensitic steel cracked#

They are annealing with an inline furnace, controlled environment with cracked amonia. The resulting surface topography of the strip after pickling could potentially 10.1149/08513. I'm also thinking there may be contamination on the surface but the annealing facility assures me this is not the case. At the electrogalvanizing line (EGL), the steel strip is generally pickled in acid before Zn plating. The annealing is done at an outside supplier so I'm sending some wire to a second annealer to see if there is any difference in the results. I can't get this low a reading unless I anneal after the first profiling step.

Their use is in stainless-steel cutting tools. No one would purchase from me.Īllowable ferrite reading (using a Ferritescope) is 5% on the wire surface. Martensitic stainless steels contain 0.10.4 carbon and 14 chromium. The SS304L is required by the specs of the tender, it's not feasible to go higher nickel. Good to hear from you EdStainless, and you also Chembros. RE: Stainless Mixed Acid Pickling (Nitric/HF) ChemBros (Chemical) I've got a huge order to produce and all the raw mats purchased but I can't send like this. These components were subjected to a temperature of 120 ☌ in the initial stages of service and had. This paper reports a case of failure of components made from martensitic SS 420 due to temper embrittlement. (and it's 304L)Īny help would be appreciated. Similar type of temper embrittlement can occur in martensitic stainless steel (SS) if tempered in the temperature range of 450-600 ☌. Please note the surface of the profiled wire is a little rougher probably due to the softness and, of course, the wire is softer. Using the same pickling solution for only 5 minutes the result is a horrible grey, uneven discoloration.

The reason for the anealing is to reduce the levels of ferrite caused during the profiling. (complete profiling to triangular shape requires 4 steps). Now we are using an SS304L (lower carbon) and adding an intra anealing step after the first profiling. The weld scales dissolve but no apparent greying of the stainless steel occurs. After profiling into a triangular shape and then resistance welding it into a screen it's cleaned (detergent) and then pickled/passivated in Hydroflouric Acia / Nitric Acid solution for approx 15 minutes. Previously we have made our wedgewire screens using (for example) a SS304 wire, diameter 4.3 mm, hardness before profiling 110 kg/mm2. I have never experienced this problem before but now there are a couple variables. I'm having a problem with grey discoloration on my stainless steel screens after pickling. It's maybe a little off the theme of this thread but here goes.